Rustamov, V. R.Kerimov, V. K.Kerimova, S. A.2018-08-022018-08-022000-10Rustamov, V. R., Kerimov, V. K., Kerimova, S. A., (2000). The scientific aspects of synthes-gas sulphur production at CO2 - H2S radiolysis processes. I. Eurasia Conference on Nuclear Science and Its Application, Presentations, Vol 2, (s. 750-754). 23-27 October 2000. İzmir, Turkey.http://kurumsalarsiv.tenmak.gov.tr/handle/20.500.12878/786I. Avrasya Nükleer Bilimler ve Uygulamaları Konferansı : 23-27 Ekim 2000. İzmir, Türkiye.The reaction of thermal and electron-excited sulphur atoms have been investigated at the radiolvsis of C02 -H2S - S8 mixtures. It was shown that thermal sulphur atoms were formed at the H2S radiolysis transform SH-radical to H2 at the thermoradiolysis of C02-H2S mixtures.Activation energy of process was equal 19.3±1.8 kj/mol. Electron excited sulphur atoms were created at the octasulphur radiolysis, participated in the tear-reaction at T = 300-320 K. Total yield of synthes-gas and sulphur was equal 13-14 mol/100eV. The present work is devoted to investigation of C02 - H2S mixtures and C02 - H2S togeneous radiolysis in the presence of powder sulphur., γ -irradiation of H2S - C02 mixtures has been carred out at the static conditions at the range of temperature 320-450K in molibdenium glassy ampoules. The doserate was determined by measuring hydrogen formation in irradiation methane (G(H2) = 5,7) and it was equal to 3 104 gy/h. Radiolysis of C02 - H2S - S8 mixtures have been carried out in silicon ampoules at the process of reagents mixing on electron accelerator ELU - 4 at T ~ 320 K. Dozimetry of accelerated electrons (E = 4 MeV, I = I mkA) was carried out measuring hydrogen formation in ethylen (G(H2) = 1,3) The rate of adsorbed doze was 5 10(2) Gy/s . Detailes of ampoules purification and filling ampoules with C02 and H2S have been given previously. At all experiments total gas pressure was 0.1 MPa.enginfo:eu-repo/semantics/openAccessCO2 - H2S radiolysis processesCO2 - H2S radyoliz işlemleriSynthes-gas sulphur productionSentez-gaz kükürt üretimiScientific aspectsBilimsel yönlericonferenceObject750754