Kinetics of the reaction of Tetrachloro-p-Benzoquinone with TRI-n-Dodecyl amine
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Date
1965-10
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
T.A.E.C. Çekmece Nuclear Research Center
Abstract
The kinetics of the reaction of chloranil with tri-n-dodecyl amine have been investigated in the temperature range 100-115.5°C and in the concentration range 0.036-0.0697 M.
The kinetics follow a simple second-order mechanism. The energy of activation is 19.7 Kcal./mole. The reaction product is a quaternary amnonium salt, (trichloro-p-benzoquinonyl)-tri-n-dodecyl ammonium chloride. The rate constant is given by:
k = 5.74 x 10(10) exp(-9950/T) (minute)(-1) (mole)(-1)
Description
TENMAK D.N.. 10310
Keywords
Kinetics -- Reaction., Kinetik -- Tepki., Energy -- Activation., Enerji -- Aktivasyon.
Citation
Erben, M. T. ve Dinçler, G. (1965). Kinetics of the reaction of Tetrachloro-p-Benzoquinone with TRI-n-Dodecyl amine. İstanbul : T.A.E.C. Çekmece Nuclear Research Center.