Browsing by All Authors "Rustamov, V. R."

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    Hydrogen production in the combined photo (radiation)-thermochemical cycle
    (Azerbaijan National Academy of Sciences Institute of Radiation Problems ve Turkish Atomic Energy Authority, 2006) Mammedova, S. A.; Garibov, A. A.; Kerimov, V. K.; AIiev, S. M.; Kurbanov, M. A.; Rustamov, V. R.; Nasirova, X. Y.; Bölüm Yok
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    Nitrogen oxidative activation in the radiolysis process of dioxide hydrocarbon composition, oxygen-nitrogen over 3-d transition metals
    (Institute of Nuclear Physics of Uzbekistan Academy of Science, Turkish Atomic Energy Authority, 2006) Rustamov, V. R.; Garibov, A. A.; Kerimov, V. K.; Aliyev, S. M.; Nasirova, Kh. Y.; Bölüm Yok
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    The scientific aspects of synthes-gas sulphur production at CO2 - H2S radiolysis processes
    (Turkish Atomic Energy Authority, 2000-10) Rustamov, V. R.; Kerimov, V. K.; Kerimova, S. A.; Bölüm Yok
    The reaction of thermal and electron-excited sulphur atoms have been investigated at the radiolvsis of C02 -H2S - S8 mixtures. It was shown that thermal sulphur atoms were formed at the H2S radiolysis transform SH-radical to H2 at the thermoradiolysis of C02-H2S mixtures.Activation energy of process was equal 19.3±1.8 kj/mol. Electron excited sulphur atoms were created at the octasulphur radiolysis, participated in the tear-reaction at T = 300-320 K. Total yield of synthes-gas and sulphur was equal 13-14 mol/100eV. The present work is devoted to investigation of C02 - H2S mixtures and C02 - H2S togeneous radiolysis in the presence of powder sulphur., γ -irradiation of H2S - C02 mixtures has been carred out at the static conditions at the range of temperature 320-450K in molibdenium glassy ampoules. The doserate was determined by measuring hydrogen formation in irradiation methane (G(H2) = 5,7) and it was equal to 3 104 gy/h. Radiolysis of C02 - H2S - S8 mixtures have been carried out in silicon ampoules at the process of reagents mixing on electron accelerator ELU - 4 at T ~ 320 K. Dozimetry of accelerated electrons (E = 4 MeV, I = I mkA) was carried out measuring hydrogen formation in ethylen (G(H2) = 1,3) The rate of adsorbed doze was 5 10(2) Gy/s . Detailes of ampoules purification and filling ampoules with C02 and H2S have been given previously. At all experiments total gas pressure was 0.1 MPa.