Browsing by All Authors "Rzayev, R."
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Item Calculation of kinetics of radiation-chemical decomposition of heptane admixtures in the water medium(National Academy of Science of Kyrgyzstan, Turkish Atomic Energy Authority, 2008) Mustafayev, I.; Ahmedli, G.; Rzayev, R.; Bölüm YokItem Radiation-thermal purification of waste water from oil pollution(Azerbaijan National Academy of Sciences Institute of Radiation Problems ve Turkish Atomic Energy Authority, 2006) Mustafayev, I.; Rzayev, R.; Guliyeva, N.; Bölüm YokIn this work the results of radiation-thermal decomposition of n-heptane micro-admixtures in water medium are adduced. The main parameters of radiolysis change within the bounds: temperature 20-400°C, absorbed dose -0÷10.8 kGy at dose rate 3.6 kGy/h. The correlation of n-heptane concentration and water steam changed within [C5H12]/[H20] = (1-100) 10(-5). Total concentration of steam was about 10(20)molec/ml. As a product of decomposition are observed H2, CO, CH4, C2H4, C2H6, C3H8, C3H6, C4H8, hydrocarbons C5+, and C6. The changes of n-heptane concentration in the reactor also were established. The chain regime of n-heptane decomposition at high temperatures in the irradiated mixture is observed. The critical value of temperature and mixture ratio of components, under which the break of chain process of normal n-heptane occurs are defined. The mechanisms of proceeding radiation thermal processes in hydrocarbons-water system are discussed.Item Radiation-thermal purification of waste water from oil pollution(Azerbaijan National Academy of Sciences Institute of Radiation Problems ve Turkish Atomic Energy Authority, 2006) Mustafayev, I.; Rzayev, R.; Guliyeva, N.; Bölüm YokIn this work the results of radiation-thermal decomposition of n-heptane micro-admixtures in water medium are adduced. The main parameters of radiolysis change within the bounds: temperature 20-400°C, absorbed dose -0÷10.8 kGy at dose rate 3.6 kGy/h. The correlation of n-heptane concentration and water steam changed within [C5H12]/[H20] = (1 -100) 10'5. Total concentration of steam was about 1020molec/ml. As a product of decomposition are observed H2, CO, CH4, C2H4, C2H6, C3H8, C3H6, C4H8, hydrocarbons C5, and C6. The changes of n-heptane concentration in the reactor also were established. The chain regime of n- heptane decomposition at high temperatures in the irradiated mixture is observed. The critical value of temperature and mixture ratio of components, under which the break of chain process of normal n-heptane occurs are defined. The mechanisms of proceeding radiation thermal processes in hydrocarbons-water system are discussed.