The synthesis, crystal structure and spectroscopic properties of a dinuclear μ–pyrazolato–N,N’–bridged dinickel(II) complex of 1,3-bis(salicylideneamino)propan–2–ol
| dc.contributor.author | Zeyrek, C. Tuğrul | |
| dc.contributor.author | Elmalı, Ayhan | |
| dc.contributor.author | Elerman, Y. | |
| dc.contributor.authorID | 0000-0001-6744-7841 | tr_TR |
| dc.contributor.department | TAEK-ANAEM | tr_TR |
| dc.date.accessioned | 2018-12-03T07:54:55Z | |
| dc.date.available | 2018-12-03T07:54:55Z | |
| dc.date.issued | 2004 | |
| dc.description.abstract | The title compound [Ni2(L)(3,5 prz)], prz = pyrazolate with the formally pentadentate ligand L = 1,3-bis(salicylideneamino)propan-2-olate, was synthesized and identified using elemental analysis and IR spectroscopy. It crystallizes in the monoclinic space group P21/c with cell parameters a = 29.873(4), b = 11.131(2), c = 13.166(3) Å , β = 107.770(10)°, V = 4169.0(13) Å3, Z = 4, Dcal = 1.618 Mg/m3. The nickel ions are bridged by the alkoxo group of the ligand and the N atoms of the μ-pyrazolate group. Each nickel(II) ion is coordinated by two N atoms and two O atoms, forming a square with trans-N2O2 geometry. The Ni···Ni distance and the Ni−O−Ni angle are 3.371(1) Å and 126.4(1)°, respectively. | tr_TR |
| dc.identifier.citation | Zeyrek, C. T. ... [ve arkadaşları]. (2004). The synthesis, crystal structure and spectroscopic properties of a dinuclear μ–pyrazolato–N,N’–bridged dinickel(II) complex of 1,3-bis(salicylideneamino)propan–2–ol. Zeitschrift für Naturforschung B, 59(8) 898-902. | tr_TR |
| dc.identifier.endpage | 902 | tr_TR |
| dc.identifier.issn | ISSN (Online) 1865-7117 | tr_TR |
| dc.identifier.issn | ISSN (Print) 0932-0776 | tr_TR |
| dc.identifier.issue | 8 | tr_TR |
| dc.identifier.startpage | 898 | tr_TR |
| dc.identifier.uri | http://kurumsalarsiv.tenmak.gov.tr/handle/20.500.12878/995 | |
| dc.identifier.volume | 59 | tr_TR |
| dc.language.iso | eng | tr_TR |
| dc.publisher | De Gruyter | tr_TR |
| dc.relation.isversionof | https://doi.org/10.1515/znb-2004-0805 | tr_TR |
| dc.relation.journal | Zeitschrift für Naturforschung B | tr_TR |
| dc.rights | info:eu-repo/semantics/openAccess | tr_TR |
| dc.subject | Crystal structure | tr_TR |
| dc.subject | Kristal yapı | tr_TR |
| dc.subject | Dinuclear complex | tr_TR |
| dc.subject | Dinükleer kompleks | tr_TR |
| dc.subject | Ni(II) ion | tr_TR |
| dc.subject | Ni (II) iyonu | tr_TR |
| dc.subject | Schiff base | tr_TR |
| dc.subject | Schiff bazı | tr_TR |
| dc.title | The synthesis, crystal structure and spectroscopic properties of a dinuclear μ–pyrazolato–N,N’–bridged dinickel(II) complex of 1,3-bis(salicylideneamino)propan–2–ol | tr_TR |
| dc.type | article | tr_TR |