Please use this identifier to cite or link to this item: http://kurumsalarsiv.tenmak.gov.tr/handle/20.500.12878/995
Title: The synthesis, crystal structure and spectroscopic properties of a dinuclear μ–pyrazolato–N,N’–bridged dinickel(II) complex of 1,3-bis(salicylideneamino)propan–2–ol
Authors: Zeyrek, C. Tuğrul
Elmalı, Ayhan
Elerman, Y.
TAEK-ANAEM
0000-0001-6744-7841
Keywords: Crystal structure
Kristal yapı
Dinuclear complex
Dinükleer kompleks
Ni(II) ion
Ni (II) iyonu
Schiff base
Schiff bazı
Issue Date: 2004
Publisher: De Gruyter
Citation: Zeyrek, C. T. ... [ve arkadaşları]. (2004). The synthesis, crystal structure and spectroscopic properties of a dinuclear μ–pyrazolato–N,N’–bridged dinickel(II) complex of 1,3-bis(salicylideneamino)propan–2–ol. Zeitschrift für Naturforschung B, 59(8) 898-902.
Abstract: The title compound [Ni2(L)(3,5 prz)], prz = pyrazolate with the formally pentadentate ligand L = 1,3-bis(salicylideneamino)propan-2-olate, was synthesized and identified using elemental analysis and IR spectroscopy. It crystallizes in the monoclinic space group P21/c with cell parameters a = 29.873(4), b = 11.131(2), c = 13.166(3) Å , β = 107.770(10)°, V = 4169.0(13) Å3, Z = 4, Dcal = 1.618 Mg/m3. The nickel ions are bridged by the alkoxo group of the ligand and the N atoms of the μ-pyrazolate group. Each nickel(II) ion is coordinated by two N atoms and two O atoms, forming a square with trans-N2O2 geometry. The Ni···Ni distance and the Ni−O−Ni angle are 3.371(1) Å and 126.4(1)°, respectively.
URI: http://kurumsalarsiv.tenmak.gov.tr/handle/20.500.12878/995
ISSN: ISSN (Online) 1865-7117
ISSN (Print) 0932-0776
Appears in Collections:Makale 2000-2009 yılları

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