Inversion of the cyanide group into iso-cyanide under gamma irradiation

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dc.contributor.authorErben, M. Talat
dc.contributor.authorÜnseren, Envare
dc.contributor.authorSeber, Nurten
dc.contributor.departmentTAEK-ÇNAEMtr_TR
dc.date.accessioned2017-09-29T06:10:36Z
dc.date.available2017-09-29T06:10:36Z
dc.date.issued1965-10
dc.descriptionTENMAK D.N.. 10300tr_TR
dc.description.abstractInfrared spectrophotometric evidence indicates that gamma irradiation of the nitriles causes partial inversion of the cyanide group into iso-cyanide according to the following mechanism: In the gamma flux, some of the cyanide groups are detached from the nitrile as cyan free radicals and, owing to their resonance-hybrid structure, .C=N - <-> - C=N., two distinct recombination processes take place leading partly to the usual cyanide and partly to the iso-cyanide, respectively. From a comparison of the optical densities at the characteristic frequency of the iso-cyanide absorption band in irradiated methacrylonitrile and ethyl iso-cyanide it is concluded that at least 20% of the cyanide groups were transformed into iso-cyanide in a specific sample of methacrylonitrile irradiated to a total dose of 0.1 megarads.tr_TR
dc.identifier.citationTalat - Erben, M., Ünseren, E. ve Seber, N. (1965). Inversion of the cyanide group into iso-cyanide under gamma irradiation. İstanbul : T.A.E.C., Çekmece Nuclear Research Center.tr_TR
dc.identifier.urihttp://kurumsalarsiv.tenmak.gov.tr/handle/20.500.12878/588
dc.language.isoengtr_TR
dc.publisherT.A.E.C., Çekmece Nuclear Research Centertr_TR
dc.relation.ispartofseriesT.A.E.C., Çekmece Nuclear Research Center;28
dc.rightsinfo:eu-repo/semantics/openAccesstr_TR
dc.subjectGamma raystr_TR
dc.subjectGama ışınlarıtr_TR
dc.subjectGamma irradiationtr_TR
dc.subjectGama ışınlamasıtr_TR
dc.titleInversion of the cyanide group into iso-cyanide under gamma irradiationtr_TR
dc.typereporttr_TR
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