The scientific aspects of synthes-gas sulphur production at CO2 - H2S radiolysis processes

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dc.contributor.authorRustamov, V. R.
dc.contributor.authorKerimov, V. K.
dc.contributor.authorKerimova, S. A.
dc.contributor.departmentBölüm Yoktr_TR
dc.date.accessioned2018-08-02T12:42:16Z
dc.date.available2018-08-02T12:42:16Z
dc.date.issued2000-10
dc.descriptionI. Avrasya Nükleer Bilimler ve Uygulamaları Konferansı : 23-27 Ekim 2000. İzmir, Türkiye.tr_TR
dc.description.abstractThe reaction of thermal and electron-excited sulphur atoms have been investigated at the radiolvsis of C02 -H2S - S8 mixtures. It was shown that thermal sulphur atoms were formed at the H2S radiolysis transform SH-radical to H2 at the thermoradiolysis of C02-H2S mixtures.Activation energy of process was equal 19.3±1.8 kj/mol. Electron excited sulphur atoms were created at the octasulphur radiolysis, participated in the tear-reaction at T = 300-320 K. Total yield of synthes-gas and sulphur was equal 13-14 mol/100eV. The present work is devoted to investigation of C02 - H2S mixtures and C02 - H2S togeneous radiolysis in the presence of powder sulphur., γ -irradiation of H2S - C02 mixtures has been carred out at the static conditions at the range of temperature 320-450K in molibdenium glassy ampoules. The doserate was determined by measuring hydrogen formation in irradiation methane (G(H2) = 5,7) and it was equal to 3 104 gy/h. Radiolysis of C02 - H2S - S8 mixtures have been carried out in silicon ampoules at the process of reagents mixing on electron accelerator ELU - 4 at T ~ 320 K. Dozimetry of accelerated electrons (E = 4 MeV, I = I mkA) was carried out measuring hydrogen formation in ethylen (G(H2) = 1,3) The rate of adsorbed doze was 5 10(2) Gy/s . Detailes of ampoules purification and filling ampoules with C02 and H2S have been given previously. At all experiments total gas pressure was 0.1 MPa.tr_TR
dc.identifier.citationRustamov, V. R., Kerimov, V. K., Kerimova, S. A., (2000). The scientific aspects of synthes-gas sulphur production at CO2 - H2S radiolysis processes. I. Eurasia Conference on Nuclear Science and Its Application, Presentations, Vol 2, (s. 750-754). 23-27 October 2000. İzmir, Turkey.tr_TR
dc.identifier.endpage754tr_TR
dc.identifier.startpage750tr_TR
dc.identifier.urihttp://kurumsalarsiv.tenmak.gov.tr/handle/20.500.12878/786
dc.language.isoengtr_TR
dc.publisherTurkish Atomic Energy Authoritytr_TR
dc.relation.journalI. Eurasia Conference on Nuclear Science and Its Application : Presentations, 23-27 October 2000. İzmir, Turkey.tr_TR
dc.rightsinfo:eu-repo/semantics/openAccesstr_TR
dc.subjectCO2 - H2S radiolysis processestr_TR
dc.subjectCO2 - H2S radyoliz işlemleritr_TR
dc.subjectSynthes-gas sulphur productiontr_TR
dc.subjectSentez-gaz kükürt üretimitr_TR
dc.subjectScientific aspectstr_TR
dc.subjectBilimsel yönleritr_TR
dc.titleThe scientific aspects of synthes-gas sulphur production at CO2 - H2S radiolysis processestr_TR
dc.typeconferenceObjecttr_TR
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